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Abstract |
Antioxidative
Activity Of Malaysian Herb Extracts In Refined, Bleached And Deodorized
Palm Olein
Malaysian herbs such as curry leaves (Murraya koenigii), kaffir lime
leaves (Citrus hystrix), pandan leaves (Pandanus amaryllifolius) and
turmeric leaves (Curcuma longa) are often used as flavourings in Malaysianfood.
They may contain various phytochemicals, which may act as antioxidants
or pro-oxidants. In order to investigate the antioxidant capacity,
the extracts of these herbs were subjected to antioxidant tests and
analysed for polyphenol content. For the accelerated oxidation study,
the ethanolic extracts were added to refined, bleached and deodorized
(RBD) palm olein and heated to 180oC for 32 hr. The polyphenol content
was observed to be highest in turmeric leaves (116.3 mg g-1 gallic
acid equivalents), followed by curry leaves (109.5 mg g-1), kaffir
lime leaves (103.2 mg g-1) and pandan leaves (101.8 mg g-1). In the
DPPH assay and the linoleic acid model system, the antioxidative activity
was highest in turmeric leaves followed by curry leaves, kaffir lime
leaves and pandan leaves. However, in heated oil, the highest activity
was observed in the sample containing curry leaf and kaffir lime leaf
extracts at 0.4% with activities comparable to that of BHT (p<0.05).
Based on the oxidative stability index (OSI), each of the herbs was
capable of retarding oxidation significantly even at 0.1% compared
to BHT (p<0.05). The results of this study suggest that these Malaysian
herbs have great potential as heat-stable antioxidants, and could
be used as alternatives to existing synthetic antioxidants.
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Removal
Of Endosulfan From Water Using Oil Palm Shell Activated Carbon And
Rice Husk Ash
In this study, the adsorption of endosulfan, a type of pesticide,
onto agricultural waste-based adsorbents, namely, oil palm shell activated
carbon (PSAC) and rice husk ash (RHA), was investigated. The as-received
adsorbents were used for batch α- and β-endosulfan adsorption
studies which included kinetics and equilibrium aspects at a constant
solution pH of 5 and at a temperature of 25ºC. It was found that
removal of β-endosulfan by both adsorbents was significantly
more efficient than that of α-endosulfan indicating a high affinity
of PSAC and RHA towards β-endosulfan. Interestingly, kinetic
equilibrium for β-endosulfan adsorption onto PSAC was achieved
after 30 min of contact time with a very high capacity of 418 mg g-1.
The adsorption kinetics data fitted the pseudo-second order model
well, implying chemisorption was the rate-controlling step. Equilibrium
adsorption data for PSAC fit the Freundlich isotherm better than the
Langmuir isotherm, suggesting the existence of multi-layer adsorption
of endosulfan on a relatively heterogeneous PSAC surface. It was found
that PSAC was efficient in removing β-endosulfan from water while
it was conversely true for RHA.
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Genetic
Variation Among Oil Palm Parent Genotypes And Their Progenies Based
On Microsatellite Markers
Knowledge on genetic distances and relationships among breeding materials
has a significant impact on crop improvement. Molecular markers are
being used increasingly to determine the genetic distance between individuals.
In this study, microsatellite markers were used to estimate the genetic
distances between selected oil palm parent lines. Microsatellite markers
are highly reliable, inherited in codominant fashion whereby heterozygotes
and homozygotes are distinguishable, easy to score and can be rapidly
produced using PCR technology. Nine microsatellite markers were used
to screen selected parent palms (15 duras and 4 pisiferas) and their
progenies (16 DxP crosses). Data were scored and analysed using the
Biosys-1 software to calculate the genetic distance values. A total
of 29 polymorphic bands were generated. The genetic distances between
progenies ranged from 0.089 to 0.313. These results indicate that microsatellite
markers are powerful tools for studying genetic relationships among
DxP progenies. These markers should be further explored to assist oil
palm breeding.
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Synthesis
Of Palmitic Acid-Based Esters And Their Effect On The Pour Point Of
Palm Oil Methyl Esters
The objectives of this research were to synthesis palmitic acid-based
esters and to study their effects on the pour point of palm oil methyl
esters. Palmitic acid was esterified with six different branched-chain
alcohols, namely 2-propanol, 2-butanol, 2-ethyl-1-hexanol, 2-methyl-1-butanol,
2-methyl-1-propanol and 2,2-dimethylpropane-1,3-diol. The purified products
were characterized by FT-IR, 1H-NMR and 13C-NMR. The effect of the six
synthesized palmitic acid-based esters on palm oil methyl esters (biodiesel)
was later evaluated. The compounds under study were isopropyl palmitate
(1), sec-butyl palmitate (2), 2-ethylhexyl
palmitate (3), 2-methylbutyl palmitate (4),
isobutyl palmitate (5) and 2,2-dimethylpropane-1,3-diyl
daipalmitate (6). All of the synthesized compounds
were miscible in palm oil methyl esters due to similar polarity of the
solute and the biodiesel. The blends of the resultant six ester compounds
in palm oil methyl esters were evaluated respectively for their effect
on pour point property. The 2,2-dimethylpropane-1,3-diyl dipalmitate
was able to improve the pour point of palm oil methyl esters from 12oC
to 9oC when 5 wt % was added.
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CantasTM
– A Tool For The Efficient Harvesting Of Oil Palm Fresh Fruit
Bunches
The Malaysian Palm Oil Board (MPOB) has developed a motorized cutter
popularly known as CantasTM for harvesting fresh fruit bunches (FFB)
at less than 4.5 m height. CantasTM is a hand-held cutter powered by
a 1.3 hp petrol engine. Trials carried out on CantasTM revealed that
the productivity of the machine was 560 to 750 bunches per day (equivalent
to 9.50 to 12.6 t day-1 at a bunch weight of 17 kg). The productivity
very much depends on the cropping level, the topography of the estate
and the operator’s skills. By comparison, the productivity of
manual harvesting (using a conventional sickle) is only 250 to 350 bunches
per day (4.20 to 6.00 t day-1). Therefore, the productivity of CantasTM
is equivalent to two to three human harvesters. Using CantasTM, the
estate would be able to reduce 50% of its labour requirement in the
harvesting operation. Another advantage of this cutter is that the terrain
or topography of estates does not restrict its usage. Saving on fringe
benefits amounts to RM 238 120 per year or RM 29 765 per person due
to savings in housing, housing maintenance, levy, electricity and water
bills, and medical leave. As for the economics of the machine, based
on the machine cost of RM 4500 per unit plus its operational, repair
and maintenance costs, the harvesting cost comes to about RM 22.10 t-1.
The cost-effectiveness was calculated at RM 0.70 t-1.
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The
Effect Of Incorporating Palm Residues At Replanting On Phosphate Dynamics
In An Inland Soil In Malaysia
The effects of adding approximately 200 mg P kg-1 soil in three different
palm residue treatments (pulverized, shredded and partially-burned)
at replanting on P fractions were investigated in a field experiment
at Kluang, Johor, two and three years after oil palm replanting. The
three treatments led to about two- to four-fold increases in the organic
P pool over the control. This indicates the importance of biological
activity, stimulated by incorporation of palm residues, in the distribution
of P fractions. Organic P and microbial P are thought to be the main
soil P fractions involved in P cycling in the soil when added through
palm residues. The results also suggest that when palm residues were
incorporated, the amount of P adsorbed was reduced by 40% to 50% after
two years and by 45% to 50%, three years after replanting. Decreasing
P sorption together with increasing P desorption in the soil is one
important aspect for improving plant P uptake efficiency. Amending the
soil with palm residues may supply a greater percentage of residual
P to oil palm. Therefore, with incorporation of palm residues, P fertilization
probably can be reduced for the two years following replanting.
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Water-In-Oil
Emulsion Of Palm Biobiesel
Emulsification technique is one of the most significant approaches
to the reduction of pollutant emission of diesel engines. In this
research, water-in-oil emulsion of palm biodiesel was prepared by
mixing palm biodiesel and water in the presence of emulsifier. For
experimental purposes, different types of emulsifiers were screened
for their effectiveness in stabilizing the emulsion system. The results
of the experiment showed that the polymeric surfactant was found to
be the most suitable emulsifier for palm biodiesel emulsion. It was
also found that the stability of the emulsion system was increased
by increasing the mixing speed. Even though the preliminary engine
test showed significant reduction of nitrogen oxides (NOx) emission,
data from this research also showed that the calorific value of the
fuel also decreased with the increase of water content in the formulation
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